Product ID:FERRIC SULFATE, P1098
MSDS Date:08/01/1989
FSC:6810
NIIN:00N058870
MSDS Number: BXFMY

VAN WATERS & ROGERS

6100 CARILLON PT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3712

Info Phone: 206-889-3712

Cage: DO735

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

IRON (III) SULFATE; (FERRIC SULFATE)

CAS: 10028-22-5

RTECS: NO8505000

Fraction By Weight: 89%

OSHA PEL 1 MG/M3 (FE)

ACGIH TLV: 1 MG/M3 (FE)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SULFURIC ACID (SARA 302/313) (CERCLA)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 2.7%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3;3 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

IN DOT-APPRVD WASTE CNTNRS. FOR LG SPILLS, SHOVEL

RTECS: 9999999ZZ

DRAINS, SURF WATERS & SOIL. COMPLY W/ALL APPLIC GOVT

RTECS: 9999999ZZ

TO PROPER WASTE DISPOSAL, AS ABOVE.

RTECS: 9999999ZZ

MODE, OR A SUPPLIED-AIR RESPIRATOR.

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1-2.3 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:DUSTS ARE CORROSIVE TO
ENTIRE RESPIRATORY TRACT. BREATHING DUST CAN DESTROY MUCOUS
MEMBRANES & CAN CAUSE SEVERE PNEUMONITIS. EYE:DUSTS ARE CORROSIVE
TO EYES. BRIEF CONTACT CAUSES SEVERE DA MAGE & PROLONGED CONTACT
CAUSES PERMANENT INJURY WHICH MAY BE FOLLOWED BY BLINDNESS.
SKIN:PROLONGED OR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID:IARC MONOGRAPHS ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 41, 1992:GRP 1. ANIMAL:PULM
IRRIT.
Effects of Overexposure:HLTH HAZ:REPEATED CONTACT W/DUST MAY IRRITATE.
INGEST:DUSTS OR SOLIDS ARE CORROSIVE TO MOUTH & THROAT. SWALLOWING
DUSTS OR SOLIDS CAUSES SEVERE & RAPID BURNING OF MOUTH, THROAT &
DIGESTIVE TRACT ACCOM PANIED BY SEVERE PAIN, VOMITING & COLLAPSE.
CHRONIC:NO SPECIFIC INFORMATION AVAILABLE.
Medical Cond Aggravated by Exposure:NONE REPORTED.

First Aid:INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BRTHG. GET
IMMED MED ATTN. EYE:IMMED FLUSH W/LOTS OF RUNNING WATER FOR AT LST
15 MINS, LIFTING UPPER & LOWER LIDS OCCAS. GET IMMED MED ATTN.
SKIN:IMMED FLUSH W/LOTS OF RUNNING WATER FOR 15 MINS. REMOVE
CONTAM CLTHG & SHOES; WASH BEFORE REUSE. GET IMMED MED ATTN.
INGEST:DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LOTS OF WATER/MILK.
GET IMMED MED(SUPDAT)

Flash Point:NONE
Extinguishing Media:THIS MATERIAL IS NOT COMBUSTIBLE. USE EXTINGUISHING
MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
USE WATER SPRAY TO COOL NEARBY CNTNRS & STRUCTURES EXPOS TO FIRE.
THIS PROD IS WATER SOL & SOLNS (SUPDAT)
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:WEAR PROT EQUIP INCL RUB BOOTS/GLOVES/APRON &
NIOSH/MSHA APPRVD SCBA IN PRESS DEMAND MODE/SUPPLIED-AIR RESP. IF
SPILL/LEAK IS SM, NIOSH/MSHA APPRVD FULL FACEPIECE AIR-PURIFYING
CARTRIDGE RESP EQUIPPED W/PARTICULATE FILTERS MAY BE SATIS.
IN(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENTILATED
PLACE AWAY FROM INCOMPAT MATLS. KEEP BAGS/FIBER DRUMS DRY AT ALL
TIMES. DO NOT GET IN EYES, ON SKIN/ON CLTHG.
Other Precautions:CORROSIVE. CNTNRS, EVEN THOSE THAT HAVE BEEN EMPTIED,
WILL RETAIN PROD RESIDUE & VAPS. ALWAYS OBEY HAZ WARNINGS & HANDLE
EMPTY CNTNRS AS IF THEY WERE FULL.

Respiratory Protection:IF USE CNDTNS GENERATE DUSTS, WEAR A NIOSH/MSHA
APPRVD RESP APPROP FOR THOSE EMISSION LEVELS. NIOSH/MSHA APPRVD
APPROP RESPS MAY BE FULL FACEPIECE/HALF MASK AIR-PURIFYING
CARTRIDGE RESP W/PARTICULATE FILTERS, SCBA IN PRESS DEMAND (ING 6)
Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING
DUST EMISSIONS AT THE POINT OF USE BELOW THE TLV.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS (ING 7)
Other Protective Equipment:LONG-SLEEVED SHIRT, TROUSERS, RUBBER BOOTS &
RUBBER APRON. EMERG EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA.
Work Hygienic Practices:WASH THORO AFTER HNDLG. IT IS GENRLY RECOGNIZED
THAT CONT LENSES SHOULD NOT BE WORN WHEN WORKING W/CHEMS BECAUSE
(ING 8)
Supplemental Safety and Health
FIRE FIGHT PROC:OF IT WILL BE ACIDIC. MIN CONT W/WATER & DO NOT ALLOW
RUN-OFF TO ENTER SEWERS, STORM DRAINS, SURF WATERS/SOIL. MATLS TO
AVOID:PAINT & ENAMEL. FIRST AID PROC:ATTN. DO NOT GIVE ANYTHING BY
MOUTH TO UNCON/CONVULSING PERS. SPILL PROC:ANY EVENT, ALWAYS WEAR
EYE PROT. FOR SM SPILLS, SWEEP UP & DISP OF (ING 3)

Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:55%
Appearance and Odor:GREY TO BROWN POWDER TO GRANULE.

Stability Indicator/Materials to Avoid:YES
WATER WILL PRDCE ACIDIC SOLN WHICH IS CORR TO MILD STEEL, GALVANIZED
STEEL, COPPER, COPPER ALLOYS, CONCRETE, (SUPP DATA)
Stability Condition to Avoid:KEEP WATER & MOIST AIR OUT OF THE
CONTAINER.
Hazardous Decomposition Products:KEEP WATER & MOIST AIR OUT OF
CONTAINER, MAY LIBERATE SULFUR TRIOXIDE AT TEMPERATURES >1000F.

Waste Disposal Methods:DISP OF CONTAM PROD & MATLS USED IN CLEANING UP
SPILLS/LEAKS IN MANNER APPRVD FOR THIS MATL. CONSULT APPROP FED,
STATE & LOC REGULATORY AGENCIES TO ASCERTAIN PROPER DISP PROCS.
NOTE:EMPTY CNTNRS CAN H AVE RESIDUES, GASES & MISTS & ARE SUBJECT
(ING 5)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.